Abstract : this article reviews recent progress in nucleophilic reactions of the - carbon in vinylidene ruthenium complexes . the nucleophiles include alkene , alkyne , alcohol , acid , amine , water , etc 文摘:综述了近几年钌亚乙烯基络合物中间体-碳的亲核反应。亲核试剂包括烯烃、炔烃、醇、酸、胺、水等。
A good electrochemical capacitance performance were proved by the tests due to that the three dimensional nanotube network of tio2 and thus will be one of approach for economizing the noble metal ruthenium 以xrd 、 tem对其进行结构与形貌表征,以循环伏安、恒流充放电以及交流阻抗测试对其进行电化学性能测试。
Professor che pioneered the chemistry of reactive ruthenium - ligand multiple bonded complexes , which he subsequently used to elucidate the mechanisms of atom and group transfer reactions with organic substrates . he discovered a series of biomimetic chemical reactions applicable to the synthesis of pharmaceuticals and fine chemicals . he also pioneered the photochemistry of phosphorescent metal complexes and synthesized , by photochemical means , novel types of reactive molecules that exhibit unique properties and reactivities unreachable by ground state molecules 支教授创立活性钌多重键配合物化学并用于揭示原子和基团向有机底物转移的反应机理开拓一系列可应用于药物合成和精细化学品合成的仿生物化学反应创立磷光金属配合物光化学，并利用光化学方法合成具有基态分子所无法达到的特殊性质和反应性的新颖物种。
The comparison of carbon nanotube and active carbon and graphite nanofibers used as electrode material is also presented . a composite electrode material comprising carbon nanotubes and ruthenium oxide is obtained and the capacitance of supercapacitor reaches 270f / g . the carbon nanotube and the natural manganese oxide compounded for the first time and the initial results were achieved 本文采用纳米碳管作为超级电容器电极材料，得到比电容量为110f g的超级电容器结构单元，讨论了粘结剂、电解液等多种影响因素，并与乙炔黑电极和鱼骨状碳纤维电极进行了对比；制备了纳米碳管与氧化钌复合材料，得到比电容量为270f g的超级电容器结构单元；本文还首次将纳米碳管与大洋锰矿复合用作超级电容器电极材料，取得了初步成果，为天然矿物的开发利用开辟了一个新的发展方向。
The free - phosphine carbene ruthenium complex [ 1 , 3 - bis ( 2 , 6 - dimethylphenyl ) - 2 - tetrahydroimidazol [ ( c5h5n ) 2 ( cl ) 2ru = chph ( 8 ) was prepared by the reaction of [ 1 , 3 - bis ( 2 , 6 - dimethylphenyl ) - 2 - tetrahydroimidazol ] ( pph3 ) ( cl ) 2ru = chph ( 7 ) with pyridine and used as a highly effective catalyst for the cross metathesis of acrylonitrile with allylbenzene 摘要设计了由1 , 3 -二（ 2 , 6 -二甲基苯基） 2 -四氢咪唑基苯亚甲基三苯基膦二氯合钌( 7 )和吡啶反应生成无膦型金属钌卡宾化合物1 , 3 -二（ 2 , 6 -二甲苯基） 2 -四氢咪唑基苯亚甲基2 -吡啶基二氯合钌( 8 ) ， 8作为高效催化剂用于丙烯腈和烯丙基苯的交叉交互置换反应。
